Functional Group Overview Continued -

Specific Examples

 

1.  Alkanes :  General Formula CnH2n+2

Examples: 

 

  CH4                   

CH3CH3

methane

ethane

propane

octane

 

 

Write the structure of decane:

 

 

 

2.  Cycloalkanes:  General Formula CnH2n

Examples

cyclopropane

cyclopentane

cycloheptane

 

 

What is the name of the following compound?

 

 

 

 

3.  Alkenes:   General Formula CnH2n

Examples:

 

ethene(ethylene)

2-butene

1-decene

 

 

Write the structure of 2-pentene.

 

 

4.  Alkynes:  General Formula CnH2n-2

Examples:

 

?

Ethyne

(acetylene)

3-hexyne

2-decyne

 

 

 

      

 

What is the name of the following compound?

 

5.Aromatics:

Examples

benzene

napthalene

anthracene

pyridine

 

 

6. Haloalkanes (alkyl halides):

Examples:

?

Chloroethane

1o

2-bromopentane

2 o

3-iodo-3methylundecane

3 o

 

 

The order  of a haloalkane and an alcohol has to do with the number of carbons directly attached  to the carbon bearing the heteroatom.   If  that carbon has three carbons the haloalkane (or alcohol) is 3 o  or tertiary , if it has two carbons it is 2 o  or secondary , etc.  It is noteworthy that carbons in alkanes can be designated similarly.  There is even a designation 4 o  or quaternary for a carbon bearing  four directly attached carbons.   These designations are useful when communicating specific information about regions of the molecules.  There is also a variation in reactivity that relates to order.

 

 

7. Alcohols

Examples:

CH3OH

CH3CH2OH

?

methanol

ethanol

2-propanol

3-methyl-3-pentanol

0 o

1 o

2 o

3 o

8.  Amines 

Examples:

?

?

ethylamine

dipropylamine

trimethylamine

 

 

9. Ethers:

Examples:

CH3OCH3

?

dimethyl ether

diethyl ether

ethylpropyl ether

 

 

Since nitrogen is a central atom, the order of the amine is defined by the number of carbons directly attached to the nitrogen.  What is the order of each the above amines?

 

 

10.   Aldehydes

Examples:

?

methanal (formaldehyde)

propanal

benzaldehyde

 

 

 

11.  Ketones:

Examples:

?

2-propanone(acetone)

3-heptanone

4-dodecanone

 

 

12. Carboxylic Acid Derivatives

a. Carboxylic Acid

Examples:

?

methanoic acid (formic acid)

ethanoic acid (acetic acid)

benzoic acid

 

 

b. Esters

Examples:

?

methyl formate (methyl methanoate)

ethyl hexanoate

 

c. Amides

Examples:

dimethyl formate (DMF, N,N-dimethyl methanoate)

 

 

 

 

d.  Anhydrides:

Examples:

?

acetic anhydride

(ethanoic anhydride)

butanoic anhydride

 

                           

 

 

e. Acyl Halides:

Examples:

?

acetylchloride  (ethanoyl chloride)

propanoyl bromide

 

                                                                                                 

              

 

f.    Nitriles:

Examples:

 

?

acetonitrile (ethanenitrile)

butanenitrile

 

 

 

 

 

 

 

Identify all the functional groups in the following molecule& .

 

 

 

 

 

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